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Runtime: Mac or Windows, 8 GB HD space required.Application of thermal isomerization to elucidation of isomer-selective gas-phase reaction mechanisms: thermal cis-trans isomerization of 1,1-diphenylethane.
Experimental and theoretical study of the thermal cis-trans isomerization of 1,1-diphenylethane has been undertaken to elucidate the mechanisms and isomer-selective behavior of the reaction. It was found that the proton affinity of the cis isomer was lower than that of the trans